In response to an aberrant increase in pitting failures in one water district in the U.S., a one day symposium on copper plumbing tube pitting was organized for technical personnel in companies which produce copper tubing and fittings, as well as others. The intent of the symposium was not to provide a solution to the pitting failures in this one water district, but rather to review the state of the knowledge in pitting in order to provide direction for future efforts. For additional background, a search of peer reviewed technical articles related to pitting is easily conducted on The Copper Data Center . The Copper Data Center is a searchable database of technical articles, to which newly published papers are added each month. For example, conducting a search with one keyword, pitting, will yield 1002 citations. Using a second keyword, water, will reduce that number to 695 and combining it with a third keyword will reduce it further to 34 references, including authors, titles, keywords and abstracts.
Over the years, analysis of failed copper tubes has been regularly conducted. As shown in Table 5 , failures related to flux corrosion are the most common mode of failure and are occurring at an increasing frequency. A great deal, but not everything, is known about corrosion of copper but theories that have little scientific basis are constantly surfacing. Some of these are listed in Table 6 .
Corrosion Cause | 1994 | 1995 | 1996 | 1997 | 1998 | 1999 | 2000 |
---|---|---|---|---|---|---|---|
Cold Water Pitting | 0 | 4 | 2 | 1 | 5 | 3 | 2 |
Concentration Cell | 6 | 5 | 3 | 4 | 3 | 8 | 15 |
Flux Corrision | 10 | 18 | 12 | 32 | 17 | 28 | 23 |
Underground Corrosion | 0 | 2 | 5 | 8 | 10 | 13 | 5 |
Green Water | 0 | 1 | 0 | 1 | 0 | 0 | 0 |
Erosion/Corrosion | 3 | 4 | 7 | 6 | 8 | 20 | 7 |
Sulfide Attack | 1 | 0 | 2 | 1 | 0 | 1 | 0 |
Stress Corrosion Cracking | 0 | 0 | 0 | 0 | 0 | 0 | 1 |
Hot Water Pitting | 3 | 2 | 5 | 11 | 14 | 10 | 5 |
Workmanship | 1 | 1 | 2 | 2 | 0 | 1 | 1 |
Glavanic Corrosion | 0 | 0 | 0 | 0 | 0 | 1 | 0 |
Total | 24 | 37 | 38 | 66 | 57 | 85 | 59 |
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